WebNov 1, 2016 · @article{Yang2016PhotonicCF, title={Photonic crystal fiber methane sensor based on modal interference with an ultraviolet curable fluoro-siloxane nano-film incorporating cryptophane A}, author={Jianchun Yang and Lang Zhou and Xin Che and Jing Huang and Xueming Li and Weimin Chen}, journal={Sensors and Actuators B-chemical}, … Cryptophanes are a class of organic supramolecular compounds studied and synthesized primarily for molecular encapsulation and recognition. One possible noteworthy application of cryptophanes is encapsulation and storage of hydrogen gas for potential use in fuel cell automobiles. Cryptophanes can … See more Cryptophanes were discovered by André Collet and Jacqueline Gabard in 1981 when these researchers created, using template-directed synthesis, the first cryptophane, now known as cryptophane-A. See more Cryptophane cages are formed by two cup-shaped [1.1.1]–orthocyclophane units (see cyclotriveratrylene), connected by three bridges (denoted Y). There are also choices of the … See more The anti cryptophane isomer belongs to the D3 point group and the syn cryptophane isomer belongs to the C3h point group. Both molecules therefore do not exhibit a dipole moment. See more
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WebMar 21, 2024 · Cryptophane is an easy-to-use Windows application that works with GnuPG (a PGP-compatible encryption program.) It allows users to encrypt, sign, decrypt, and … WebNew enantiopure cryptophanes 3−7 having C1-symmetry have been synthesized. Electronic circular dichroism (ECD) and vibrational circular dichroism (VCD) have been used to investigate their chiroptical properties, and the results are compared to those obtained for cryptophane-A (1) having D3-symmetry. The ECD spectra of compounds 3−7 show Cotton … nothingface skeletons
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WebCryptophane-A has two identical caps, carrying a methoxygrouponeachphenylgroup.CryptophanesCandDhave the caps different—one carrying the methoxy substituents on the phenyl groups and one containing unsubstituted phenyl units (see Scheme 1). They are diastereoisomers—cryptophane-C is the anti isomer (in … WebAug 10, 2016 · Abstract. We report a (129)Xe NMR relaxation-based sensing approach that exploits changes in the bulk xenon relaxation rate induced by slowed tumbling of a cryptophane-based sensor upon target binding. The amplification afforded by detection of the bulk dissolved xenon allows sensitive detection of targets. The sensor comprises a … WebJan 20, 2024 · The graphene, nickel nanoparticles and Cryptophane-A were combined with SAW technology, and deposited the graphene–nickel–Cryptophane-A sensitive film on the SAW resonator with a central frequency of 204.3 MHz. The deposition process is shown in Figure 4. Figure 4. Sensitive film deposition process. how to set up voicemail on windstream